<i>Ortho</i>-aryl substituted DPEphos ligands: rhodium complexes featuring C–H anagostic interactions and B–H agostic bonds
نویسندگان
چکیده
Rh(i) complexes of ortho-substituted DPEphos-R (R = H, Me, OMe, iPr) ligands show anagostic interactions; for R =iPr C–H activation/dehydrogenative borylation forms a product exhibiting both B–H/Rh 3c-2e agostic and C–H/Rh motifs.
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ژورنال
عنوان ژورنال: Chemical Science
سال: 2021
ISSN: ['2041-6520', '2041-6539']
DOI: https://doi.org/10.1039/d1sc01430g